What is the effect of heat on some raw materias?

Unit 1 Topic 12
Glaze Basics

Many raw materials break down into oxides when heated during the firing process.

In the following example the whiting (CaCO3) molecule breaks down into two oxides when heated to 825 deg. C. The carbon dioxide (CO2) gas bubbles out of the molten glass leaving the flux calcium oxide which lowers the melting point of the glass formers.
whiting
(calciumcarbonate)
heated to
825 deg.C
>>>
calcium
oxide

+

carbon
dioxide
 
CaCO3
>>>>>>>>>>
CaO
CO2
 
     
Flux oxide
remains in the glaze.
 
Bubbles out of the
glaze as a gas.
 

When whiting is mixed with other oxides the melting point of the mixture may be
lower than 825 deg.C.

The melting point of a group of oxides together is called the group's eutectic.

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